Title holders Liverpool have been paired with Atletico Madrid in the UEFA Champions League Round of 16 held on Monday.
Chelsea, meanwhile, face a tough test after being paired with five-time champions, Bayern Munich, a repeat of 2012 final.
Manchester City will face 13-time winners, Real Madrid, while Tottenham will face RB Leipzig in the first knockout round.
The first legs will take place between February 18-19, with the return matches holding the following week.
FULL LAST 16 DRAW
Borussia Dortmund v Paris Saint-Germain
Real Madrid v Manchester City
Atalanta v Valencia
Atletico Madrid v Liverpool
Chelsea v Bayern Munich
Lyon v Juventus
Tottenham v RB Leipzig
Napoli v Barcelona